Step 1. Preheat oven to 425°F (220°C). Line a 12-cup muffin tin with paper liners.
Step 2. In a large bowl, whisk together flour, cocoa, sugar, baking soda, salt, espresso powder (if using), and chocolate chips.
Step 3. In a separate bowl, whisk eggs, sour cream/yogurt, milk, oil, and vanilla until smooth.
Step 4. Pour wet mixture into the dry ingredients. Fold gently until just combined — the batter will be thick. Do not overmix.
Step 5. Divide batter evenly into muffin cups, filling them almost to the top.
Step 6. Bake for 5 minutes at 425°F, then reduce oven temperature to 350°F (175°C) and continue baking for 14–16 minutes, until a toothpick comes out with moist crumbs.
Step 7. Cool muffins in the pan for 5 minutes, then transfer to a wire rack. Enjoy warm for gooey chocolate chips!